Control of absorption properties of tetraazaporphyrin group 15 complexes by modification of their axial ligands.

نویسندگان

  • Taniyuki Furuyama
  • Mitsuo Asai
  • Nagao Kobayashi
چکیده

Tetraazaporphyrin (TAP) complexes with group 15 elements (phosphorus(v) or arsenic(v)) containing two axial OH ligands showed reversible spectroscopic changes with acid or base doping. Spectroscopic and theoretical analysis revealed that the modification of axial ligands can tune the interaction between peripheral substituents and the TAP macrocycle.

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عنوان ژورنال:
  • Chemical communications

دوره 50 95  شماره 

صفحات  -

تاریخ انتشار 2014